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Problem 1

The IUPAC name of \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COCl}\) is (a) benzoyl chloride (b) benzene chloroketone (c) benzene carbonyl chloride (d) chlorophenyl ketone

Problem 2

In the reaction, \(\mathrm{CH}_{3} \mathrm{CHO}+\mathrm{HCN} \longrightarrow \mathrm{CH}_{3} \mathrm{CH}(\mathrm{OH}) \mathrm{CN}\) a chiral centre is produced. This product would be (a) racemic mixture (b) meso compound (c) dextrorotatory (d) laevorotatory

Problem 3

Optical activity is measured by (a) refractometer (b) tracer technique (c) spectrograph (d) polarimeter

Problem 4

The compound having only primary hydrogen atoms is (a) isobutene (b) 2,3 -dimethyl but-2-ene (c) cyclohexane (d) propyne

Problem 5

Which of the following shows geometrical isomerism? (a) but-1-ene (b) but-2-ene (c) 2,3 -dichlorobutane (d) ethene

Problem 6

The number of optically active isomers of tartaric acid is CC(O)C(=O)O (a) 2 (b) 3 (c) 4 (d) 1

Problem 7

The compound in which \(\mathrm{C}\) uses only its \(\mathrm{sp}^{3}\) hybrid orbitals for bond formation is (a) \(\mathrm{HCOOH}\) (b) \(\left(\mathrm{NH}_{2}\right)_{2} \mathrm{CO}\) (c) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{COH}\) (d) \(\mathrm{CH}_{3} \mathrm{CHO}\)

Problem 8

Number of isomers which can be obtained theoretically from monochlorination of 2 -methylbutane are (a) 2 (b) 3 (c) 4 (d) 5

Problem 9

An organic molecule necessarily shows optical activity if it (a) is non-superimposable on its mirror image (b) is superimposable on its mirror image (c) contains asymmetric carbon atoms (d) is non-polar

Problem 10

The C-H bond distance is longest in (a) \(\mathrm{C}_{2} \mathrm{H}_{2}\) (b) \(\mathrm{C}_{2} \mathrm{H}_{4}\) (c) \(\mathrm{C}_{2} \mathrm{H}_{6}\) (d) \(\mathrm{C}_{2} \mathrm{H}_{2} \mathrm{Br}_{2}\)

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