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An electron is bound in a square well of width 1.50nmand depth U0=6E1-IDW. If the electron is initially in the ground level and absorbs a photon, what maximum wavelength can the photon have and still liberate the electron from the well?

Short Answer

Expert verified

The maximum wavelength can the photon have and still liberate the electron from the well is1.38μm.

Step by step solution

01

Define the energy level.

The energy level of a particle of massmin a box of widthLis:

En=Pn22m=n2h28mL=n2Ï€2h22mL(n=1,2,3...)

The ground state energy as a fraction of the ground-level energy for an infinitely deep well E1-1DWis given by:

E1=0.625E1-1DW

The difference between the energy of the ground level and the depth of the potential well is equal to the minimum energy required for photon to release the electron.

Emin=U0-E1

The energy of photon E=hcλwhere, λis the wavelength.

02

Determine the minimum energy.

Given that, the energy level of square well of depth isU0=6E1-1DWand the width of well is1.50nm=1.50×10-9m.

The mass of electron is9.11×10-31kgand value ofh=1.055×10-34J⋅s.

The minimum energyEmin:

localid="1664000583493" Emin=6E1-1DW-0.625E1-1DW=5.375E1-1DW=5.375π2h22mL2=5.375π21.055×10-3429.11×10-311.50×10-9=1.44×10-19J

Hence, the minimum energy required for photon to release the electron is1.44×10-19J.

03

Determine the wavelength of photon.

The speed cof light is 3.00×108m/sand the Planck’s constant is localid="1664000733663" 6.626×1034J⋅s.

The wavelength of photon λis:

λ=hcEmin

=6.26×10-343.00×1081.44×10-19=1.38×106m=1.38μm

Hence, the maximum wavelength can the photon have and still liberate the electron from the well is 1.38μm.

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