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Use a computer to produce a table and graph, like those in this section, for the case where one Einstein solid contains 200 oscillators, the other contains100 oscillators, and there are 100 units of energy in total. What is the most probable macrostate, and what is its probability? What is the least probable macrostate, and what is its probability?

Short Answer

Expert verified

The most likely macrostate is when 67energy units out of the total energy units are in solid A,qA=67and qB=33, with a probability of 0.07315; the least likely macrostate is when all energy units are in partitionBqA=0or when qB=100, with a probability of 2.6926×10-37.

Step by step solution

01

Calculation for overall multiplicity

Probability is,

PqA=ΩAΩBΩoverall

Over all multiplicity is,

ΩoverallNoverall,qoverall=qoverall+Noverall-1qoverall

=qoverall+Noverall-1!qoverall!Noverall-1!

Where,

qoverall=qA+qB=100

Noverall=NA+NB=300

Then,

Ωoverall=100+300-1100

=(100+300-1)!100!(300-1)!

=1.681×1096

02

Calculation for total multiplicity and probability

Total multiplicity is,

Ωtotal=ΩAΩB

NA=200

ΩA=qA+199qA

=qA+199!qA!(199!)

ΩB=qB+NB-1qB

For NB=100,qB=100-qA

ΩB=100-qA+100-1100-qA

=199-qA!100-qA!(99)!

probability is,

PqA=ΩAΩBΩoverall

=11.681×1096qA+199!qA!(199!)199-qA!100-qA!(99)!

PqA=11.681×1096qA+199!qA!(199!)199-qA!100-qA!(99)!

03

Python program for creation of graph

04

Graph for probability versus energy

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